A versatile new monomer family:: Functionalized 4-vinyl-1,2,3-triazoles via click chemistry

被引:158
|
作者
Thibault, Raymond J.
Takizawa, Kenichi
Lowenheilm, Peter
Helms, Brett
Mynar, Justin L.
Frechet, Jean M. J.
Hawker, Craig J. [1 ]
机构
[1] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA
[2] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
[3] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
关键词
D O I
10.1021/ja0648209
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Using facile, highly modular synthetic approaches, a new monomer family based on a 1,2,3-triazole-4-vinyl building block has been prepared, and various functional derivatives have been obtained. Subsequent homo- and copolymerization of these novel functionalized monomers gives polymeric materials with unique physical properties, combining many attractive features of more traditional monomers, such as styrene, vinylpyridine, and meth/acrylates. Copyright © 2006 American Chemical Society.
引用
收藏
页码:12084 / 12085
页数:2
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