A versatile new monomer family:: Functionalized 4-vinyl-1,2,3-triazoles via click chemistry

被引:158
|
作者
Thibault, Raymond J.
Takizawa, Kenichi
Lowenheilm, Peter
Helms, Brett
Mynar, Justin L.
Frechet, Jean M. J.
Hawker, Craig J. [1 ]
机构
[1] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA
[2] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
[3] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
关键词
D O I
10.1021/ja0648209
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Using facile, highly modular synthetic approaches, a new monomer family based on a 1,2,3-triazole-4-vinyl building block has been prepared, and various functional derivatives have been obtained. Subsequent homo- and copolymerization of these novel functionalized monomers gives polymeric materials with unique physical properties, combining many attractive features of more traditional monomers, such as styrene, vinylpyridine, and meth/acrylates. Copyright © 2006 American Chemical Society.
引用
收藏
页码:12084 / 12085
页数:2
相关论文
共 50 条
  • [1] Click Chemistry: 1,2,3-Triazoles as Pharmacophores
    Agalave, Sandip G.
    Maujan, Suleman R.
    Pore, Vandana S.
    CHEMISTRY-AN ASIAN JOURNAL, 2011, 6 (10) : 2696 - 2718
  • [2] A Cu(II)-Inorganic Co-Crystal as a Versatile Catalyst Towards 'Click' Chemistry for Synthesis of 1,2,3-triazoles and β-hydroxy-1,2,3-triazoles
    Ghosh, Debasish
    Dhibar, Subhendu
    Dey, Amiya
    Manna, Priyanka
    Mahata, Partha
    Dey, Biswajit
    CHEMISTRYSELECT, 2020, 5 (01): : 75 - 82
  • [3] Neoglycopolymers Based on 4-Vinyl-1,2,3-Triazole Monomers Prepared by Click Chemistry
    Hetzer, Martin
    Chen, Gaojian
    Barner-Kowollik, Christopher
    Stenzel, Martina H.
    MACROMOLECULAR BIOSCIENCE, 2010, 10 (02) : 119 - 126
  • [4] Beyond click chemistry - supramolecular interactions of 1,2,3-triazoles
    Schulze, Benjamin
    Schubert, Ulrich S.
    CHEMICAL SOCIETY REVIEWS, 2014, 43 (08) : 2522 - 2571
  • [5] The Sequential Sonogashira-Click Reaction: A Versatile Route to 4-Aryl-1,2,3-triazoles
    Lorincz, Krisztian
    Kele, Peter
    Novak, Zoltan
    SYNTHESIS-STUTTGART, 2009, (20): : 3527 - 3532
  • [6] Study on the green click-chemistry synthesis of 4-trifluoroacetyl-1,2,3-triazoles
    Han, Jie
    Ran, Jian-Xiong
    Chen, Xiu-Ping
    Wang, Zhong-Hua
    Wu, Fan-Hong
    TETRAHEDRON, 2018, 74 (49) : 6985 - 6992
  • [7] CLICK CHEMISTRY ON POLYMER SUPPORT: SYNTHESIS OF 1-VINYL- AND 1-ALLYL-1,2,3-TRIAZOLES VIA SELENIUM LINKER
    Wang, Qiu-Ying
    Sheng, Wu-Sheng
    Sheng, Shou-Ri
    Li, Yan
    Cai, Ming-Zhong
    SYNTHETIC COMMUNICATIONS, 2014, 44 (01) : 59 - 67
  • [8] 1,2,3-Triazoles by Click Chemistry using Azido Esters as a Precursor
    Kumari, Dimple
    Banerjee, Shaibal
    PROPELLANTS EXPLOSIVES PYROTECHNICS, 2020, 45 (12) : 1845 - 1852
  • [9] Facile synthesis of 4-vinyl- and 4-fluorovinyl-1,2,3-triazoles via bifunctional "click-olefination" reagents
    Kumar, Rakesh
    Pradhan, Padmanava
    Zajc, Barbara
    CHEMICAL COMMUNICATIONS, 2011, 47 (13) : 3891 - 3893
  • [10] Green synthesis of 1-monosubstituted 1,2,3-triazoles via 'click chemistry' in water
    Wu, Luyong
    Yan, Bo
    Yang, Guo
    Chen, Yuxue
    HETEROCYCLIC COMMUNICATIONS, 2013, 19 (06) : 397 - 400