Preparation of trimetallic electrocatalysts by one-step co-electrodeposition and efficient CO2 reduction to ethylene

Use of multi-metallic catalysts to enhance reactions is an interesting research area, which has attracted much attention. In this work, we carried out the first work to prepare trimetallic electrocatalysts by a one-step co-electrodeposition process. A series of Cu-X-Y (X and Y denote different metals) catalysts were fabricated using this method. It was found that Cu10La1Cs1 (the content ratio of Cu2+, La3+, and Cs+ in the electrolyte is 10 : 1 : 1 in the deposition process), which had an elemental composition of Cu10La0.16Cs0.14 in the catalyst, formed a composite structure on three dimensional (3D) carbon paper (CP), which showed outstanding performance for CO2 electroreduction reaction (CO2RR) to produce ethylene (C2H4). The faradaic efficiency (FE) of C2H4 could reach 56.9% with a current density of 37.4 mA cm(-2) in an H-type cell, and the partial current density of C2H4 was among the highest ones up to date, including those over the catalysts consisting of Cu and noble metals. Moreover, the FE of C2+ products (C2H4, ethanol, and propanol) over the Cu10La1Cs1 catalyst in a flow cell reached 70.5% with a high current density of 486 mA cm(-2). Experimental and theoretical studies suggested that the doping of La and Cs into Cu could efficiently enhance the reaction efficiency via a combination of different effects, such as defects, change of electronic structure, and enhanced charge transfer rate. This work provides a simple method to prepare multi-metallic catalysts and demonstrates a successful example for highly efficient CO2RR using non-noble metals.