Kinetics and dynamic adsorption of methylene blue by CO2-activated resorcinol formaldehyde carbon gels

The present work is aimed at evaluating the kinetics and dynamic adsorption of methylene blue by CO2-activated carbon gels. The carbon gels were characterized by textural properties, thermal degradation and surface chemistry. The result shows that the carbon gels are highly microporous with surface area of 514 m(2)/g and 745 m(2)/g for resorcinol-to-catalyst ratios of 1000 (AC1) and 2000 (AC2), respectively. The kinetics data could be described by pseudo-first-order model, with a longer duration to attain equilibrium due to restricted pore diffusion as concentration increases. Also, AC1 exhibits insignificant kinetics with fluctuating adsorption with time at concentrations of 20 and 25 mg/L. However, AC1 reveals a better performance than AC2 in dynamic adsorption due to concentration gradient for molecules diffusion to active sites. The applicability of Yoon-Nelson and Thomas models indicates that the dynamic adsorption is controlled by external and internal diffusion.