Thin RF sputtered and thermal Ta2O5 on Si for high density DRAM application

Tantalum pentoxide thin films on Si prepared by two conventional for modern microelectronics methods (RF sputtering of Ta in Ar + O-2 mixture and thermal oxidation of tantalum layer on Si) have been investigated with respect to their dielectric, structural and electric properties. It has been found that the formation of ultra thin SiO2 firm at the interface with Si, during fabrication implementing the methods used, is unavoidable as both, X-ray photoelectron spectroscopy and electrical measurements, have indicated. The initial films (as-deposited and as-grown) are not perfect and contain suboxides of tantalum and silicon which act as electrical active centers in the form of oxide charges and interface states. Conditions which guarantee obtaining high quality tantalum oxide with dielectric constant of 32-37 and leakage current density less than 10(-7) A/cm(2) at 1.5 V applied voltage (Ta2O5 thickness equivalent to about 3.5 nm of SiO2) have been established. These specifications make the layers obtained suitable alternative to SiO2 for high density DRAM application. (C) 1999 Elsevier Science Ltd. All rights reserved.