New possibilities for efficient effect of charge transport in phthalide-containing poly(arylene ether ketones)

被引：12

作者：

Ponomarev, A. F. ^{[1
]}

Moshelev, A. V. ^{[1
]}

Il'yasov, V. Kh. ^{[1
]}

Lachinov, A. N. ^{[2
]}

Salazkin, S. N. ^{[3
]}

Shaposhnikova, V. V. ^{[3
]}

Sharapov, D. S. ^{[3
]}

Kornilov, V. M. ^{[2
]}

机构：

[1] Birsk State Social & Pedag Acad, Birsk 452320, Bashkortostan, Russia

[2] Russian Acad Sci, Ufa Res Ctr, Inst Phys Mol & Crystals, Ufa 450075, Russia

[3] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

来源：

POLYMER SCIENCE SERIES C | 2009年 / 51卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

Polymer Science Series; DMAA; Electrophysical Property; Phthalide; Dielectric State;

D O I：

10.1134/S1811238209010081

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Random phthalide-containing poly(arylene ether ketones) have been synthesized. The properties of the polymers have been studied by the thermostimulated-current and thermostimulated-depolarization methods. An extremal dependence of the electrophysical properties on the content of phthalide groups in macromolecules is observed with a maximum at their concentration of 10-15%. These dependences are explained in terms of the Sworakowski model in which the role of polarization energy of phthalide-containing molecular fragments is distinguished. The feasibility of targeted variations in the electrophysical properties of nonconjugated polymers through incorporation of functional blocks into them is discussed.

引用

页码：46 / 50

页数：5

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