One-Pot Synthesis of Poly(linoleic acid)-g-Poly(styrene)-g-Poly(ε-caprolactone) Graft Copolymers

被引：24
|
作者：
Alli, Abdulkadir [1 ]
Alli, Sema [1 ,2 ]
Becer, C. Remzi [3 ]
Hazer, Baki [2 ]
机构：
[1] Duzce Univ, Dept Chem, TR-81620 Duzce, Turkey
[2] Bulent Ecevit Univ, Dept Chem, TR-67100 Zonguldak, Turkey
[3] Queen Mary Univ London, Sch Engn & Mat Sci, London E1 4NS, England
来源：
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY | 2014年 / 91卷 / 05期
关键词：
Autoxidation; One-pot polymerization; epsilon-Caprolactone; Polymeric linoleic acid peroxides; RING-OPENING POLYMERIZATION; FRAGMENTATION CHAIN-TRANSFER; ONE-STEP SYNTHESIS; MIKTOARM STAR COPOLYMERS; BLOCK-COPOLYMERS; METHYL-METHACRYLATE; RAFT POLYMERIZATION; MECHANISM TRANSFORMATION; RADICAL POLYMERIZATION; SHAPED COPOLYMERS;
D O I：
10.1007/s11746-014-2418-1
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
One-pot synthesis of graft copolymers by ring-opening polymerization and free radical polymerization using polymeric linoleic acid peroxide (PLina) is reported. Graft copolymers having structures of poly(linoleic acid)-g-polystyrene-g-poly(epsilon-caprolactone) were synthesized from PLina, possessing peroxide groups on the main chain by the combination of free radical polymerization of styrene and ring-opening polymerization of epsilon-caprolactone in one-step. Principal parameters, such as monomer concentration, initiator concentration, and polymerization time, which effect the one-pot polymerization reactions were evaluated. The obtained graft copolymers were characterized by H-1-NMR and DOSY-NMR spectroscopy, gel permeation chromatography, thermal gravimetric analysis and differential scanning calorimetry techniques.
引用
收藏
页码：849 / 858
页数：10
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