Stereoselective total synthesis of microcarpalide

被引：20
|
作者：
Sharma, G. V. M. [1 ]
Cherukupalli, Govardhan R. [1 ]
机构：
[1] Indian Inst Chem Technol, Discovery Lab, Hyderabad 50000, Andhra Pradesh, India
来源：
TETRAHEDRON-ASYMMETRY | 2006年 / 17卷 / 07期
关键词：
D O I：
10.1016/j.tetasy.2006.03.024
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A stereoselective total synthesis of microcarpalide using ring-closing metathesis (RCM) as a key step is reported. L-Ascorbic acid was used as a chiral pool material for the construction of the olefinic alcohol and an asymmetric aldol reaction provided the chiral precursor for the synthesis of olefinic acid. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1081 / 1088
页数：8
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