Calculation of Gibbs energies of hydration of monovalent ions: Examination of born equation and its reevaluation

被引：15

作者：

Lahiri, SC ^{[1
]}

机构：

[1] Univ Kalyani, Dept Chem, Kalyani 741235, W Bengal, India

来源：

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS | 2000年 / 214卷 / 01期

关键词：

born equation; defects and reevaluation; modified method of calculation; Gibbs energies of hydration of ions;

D O I：

10.1524/zpch.2000.214.1.027

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The limitations of Born equation and its different modifications for the calculation of Gibbs energies of hydration of ions have been briefly reviewed. A modified method for the calculation of hydration energies of ions has been suggested. The hydration energies thus obtained have been compared with the data in the literature.

引用

页码：27 / 44

页数：18

共 25 条

[21] An experimental verification of Gibbs' adsorption equation by observing the absorption by mercury of its own ions from solution, and its bearing on Nernst's theory of electrode potential.
Schofield, RK
PHILOSOPHICAL MAGAZINE, 1926, 1 (03): : 641 - 658
[22] THE APPLICATION OF EQUATION OF STATE BY VANDERWAALS - BERTHELOT AND GUGGENHEIM FOR THE CALCULATION OF THERMODYNAMIC EXCESS PROPERTIES IN BINARY-MIXTURES OF NON-ELECTROLYTES .3. INVESTIGATIONS FOR PREDICTION OF GIBBS FREE-ENERGIES AND ENTHALPIES OF MIXIN
SUHNEL, K
CHEMISCHE TECHNIK, 1981, 33 (12): : 646 - 648
[23] Calculation of electronic energies and vibrational levels of molecular ions from theHamilton-Jacobi equation:: H2+, D2+, T2+, HD+ and DT+
Campos, J. A.
Nascimento, D. L.
Wolf, M.
Fonseca, A. L. A.
Nunes, O. A. C.
JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 2006, 769 (1-3): : 39 - 46
[24] THE APPLICATION OF EQUATION OF STATE BY VANDERWAALS, BERTHELOT AND GUGGENHEIM FOR THE CALCULATION OF THERMODYNAMIC EXCESS PROPERTIES IN BINARY-MIXTURES OF NON-ELECTROLYTES .2. THE MODELING OF GIBBS FREE-ENERGIES AND ENTHALPIES AND VOLUMES OF MIXING OF N-PARAFFINE SYSTEMS WITH DIFFERENT POLAR COMPONENTS
SUHNEL, K
SEYFFERT, U
CHEMISCHE TECHNIK, 1981, 33 (08): : 417 - 420
[25] Determination of the absolute values of Gibbs energy of hydration or solvation ΔGabs0(M+or X-)h or s of monovalent (alkali metal and halide) ions and other thermodynamic parameters in aqueous and non-aqueous solvents using a single standard state and analysis of ΔGabs0(M+ or X-)h or s values based on cluster-ion solvation method
Bhattacharyya, Ranjana
Lahiri, S. C.
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2008, 85 (12) : 1249 - 1268

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