Practical synthesis of an L-fructose-derived ketone catalyst for asymmetric epoxidation of olefins

被引：50
|
作者：
Zhao, Mei-Xin [1 ]
Shi, Yian [1 ]
机构：
[1] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2006年 / 71卷 / 14期
关键词：
D O I：
10.1021/jo060335k
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An L-fructose-derived ketone catalyst for asymmetric epoxidation of trans- and trisubstituted olefins was efficiently prepared from L-sorbose in five steps.
引用
收藏
页码：5377 / 5379
页数：3
相关论文
共 50 条
  • [21] Organocatalytic oxidation: Development of ketone catalysts for asymmetric epoxidation of olefins with broad scope.
    Shi, Y
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 228 : U71 - U71
  • [22] Asymmetric Epoxidation of Olefins Catalyzed by Substituted Aminobenzimidazole Manganese Complexes Derived from L-Proline
    Tian, Jing
    Lin, Jin
    Zhang, Jisheng
    Xia, Chungu
    Sun, Wei
    ADVANCED SYNTHESIS & CATALYSIS, 2022, 364 (03) : 593 - 600
  • [23] Synthesis of Bulky Epoxides via Asymmetric Epoxidation of Bulky Olefins
    Sun Yun-Kai
    Yang Nian-Fa
    Wu Shi
    Ling Ying
    Ouyang Kun-Bing
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2009, 30 (08): : 1559 - 1565
  • [24] Asymmetric epoxidation by chiral ketones derived from carbocyclic analogues of fructose
    Wang, ZX
    Miller, SM
    Anderson, OP
    Shi, Y
    JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (02): : 521 - 530
  • [25] Studies on the synthesis of terpene-derived chiral ketone and iminium salt catalysts for asymmetric olefin epoxidation
    Overly, Kenneth
    Williams, Christine
    Bouchard, Jocelyn
    Trainor, Alison
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249
  • [26] Biomimetic catalyst: Salen-metal complex catalyzed asymmetric epoxidation of the olefins
    Zhou, ZM
    Li, LY
    Xu, Q
    Yu, CX
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2005, 25 (04) : 347 - 354
  • [27] A practical and simple method of recycling catalyst in asymmetric aminohydroxylation of Olefins
    Sun, Xiao Li
    Jin, Ying
    He, Wei
    Nan, Peng Juan
    Zhang, Sheng Yong
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2007, 28 (08) : 1422 - 1424
  • [28] Synthesis of (+)-Ambrisentan via Chiral Ketone-Catalyzed Asymmetric Epoxidation
    Peng, Xianyou
    Li, Peijun
    Shi, Yian
    JOURNAL OF ORGANIC CHEMISTRY, 2012, 77 (01): : 701 - 703
  • [29] Organocatalytic asymmetric epoxidation of olefins catalyzed by chiral ketones derived from carbohydrates
    Wang Chun
    Gao Yongjun
    Zhang Yingqun
    Wang Zhi
    Ma Jingjun
    PROGRESS IN CHEMISTRY, 2006, 18 (06) : 761 - 767
  • [30] Design and synthesis of chiral ketones for catalytic asymmetric epoxidation of unfunctionalized olefins
    J Am Chem Soc, 24 (5943-5952):
12345