The lithium environment in lithium diborate glass studied by neutron diffraction with isotopic substitution of Li

被引：9

作者：

Majérus, O

Cormier, L

Calas, G

Soper, AK

机构：

[1] Univ Paris 06, CNRS, UMR 7590, Lab Mineral Cristallog Paris, F-75251 Paris 05, France

[2] Univ Paris 07, CNRS, UMR 7590, Lab Mineral Cristallog Paris, F-75251 Paris 05, France

[3] Rutherford Appleton Lab, ISIS Sci Div, Didcot OX11 0QX, Oxon, England

来源：

PHYSICA B-CONDENSED MATTER | 2004年 / 350卷 / 1-3期

关键词：

glasses; isotope substitution; neutron diffraction;

D O I：

10.1016/j.physb.2004.04.043

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

The Li environment has been determined in a Lithium diborate glass by using neutron diffraction with isotopic substitution of Li. In the first difference function, oscillations are discernible up to 20 Angstrom(-1). Li appears in a strongly distorted tetrahedral site, with an average Li-O distance of 1.99 Angstrom second peak at 2.96 Angstrom is assigned to Li-B correlations and indicates dominant connections by corners between the Li polyhedra and the borate units. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：258 / 261

页数：4

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