Molecular and crystal structure of quinoline-2-aldehyde thiosemicarbazone

被引：16

作者：

Bourosh, P. N. ^{[1
]}

Revenko, M. D. ^{[2
]}

Gdaniec, M. ^{[3
]}

Stratulat, E. F. ^{[2
]}

Simonov, Yu. A. ^{[1
]}

机构：

[1] Moldavian Acad Sci, Inst Appl Sci, Kishinev, Moldova

[2] Moldova State Univ, Kishinev, Moldova

[3] Adam Mickiewicz Univ, Fac Chem, Poznan, Poland

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2009年 / 50卷 / 03期

关键词：

quinoline-2-aldehyde thiosemicarbazone; synthesis; structure; configuration; crystal structure; METAL-COMPLEXES; SALICYLALDEHYDE; SEMICARBAZONES; COPPER(II);

D O I：

10.1007/s10947-009-0078-z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The molecular and crystal structure of quinoline-2-aldehyde thiosemicarbazone is determined. The thiosemicarbazide fragment has cis-arrangement of terminal nitrogen atoms relative to the central N-C bond. The structure is based on a centrosymmetric dimer formed by hydrogen bonds between NH groups and sulfur atoms of thiosemicarbazide fragments of the neighboring molecules. In the crystal, the dimers are joined with each other through a system of hydrogen bonds and intermolecular pi-pi interactions.

引用

页码：510 / 513

页数：4

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