Molecular and crystal structure of quinoline-2-aldehyde thiosemicarbazone

被引：16
|
作者：
Bourosh, P. N. [1 ]
Revenko, M. D. [2 ]
Gdaniec, M. [3 ]
Stratulat, E. F. [2 ]
Simonov, Yu. A. [1 ]
机构：
[1] Moldavian Acad Sci, Inst Appl Sci, Kishinev, Moldova
[2] Moldova State Univ, Kishinev, Moldova
[3] Adam Mickiewicz Univ, Fac Chem, Poznan, Poland
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2009年 / 50卷 / 03期
关键词：
quinoline-2-aldehyde thiosemicarbazone; synthesis; structure; configuration; crystal structure; METAL-COMPLEXES; SALICYLALDEHYDE; SEMICARBAZONES; COPPER(II);
D O I：
10.1007/s10947-009-0078-z
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The molecular and crystal structure of quinoline-2-aldehyde thiosemicarbazone is determined. The thiosemicarbazide fragment has cis-arrangement of terminal nitrogen atoms relative to the central N-C bond. The structure is based on a centrosymmetric dimer formed by hydrogen bonds between NH groups and sulfur atoms of thiosemicarbazide fragments of the neighboring molecules. In the crystal, the dimers are joined with each other through a system of hydrogen bonds and intermolecular pi-pi interactions.
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页码：510 / 513
页数：4
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