Free-radical polymerization of styrene and butyl methacrylate in the presence of [bis(triphenylphosphino)(3,6-di-tert-butylbenzosemiquinone-1,2)copper(I)]1

被引：0

作者：

Kopylova, NA

Spirin, SG

Cherkasov, VK

Krashilina, AV

Semchikov, YD

Abakumov, GA

机构：

[1] Nizhni Novgorod State Univ, Nizhnii Novgorod 603950, Russia

[2] Russian Acad Sci, Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603950, Russia

来源：

POLYMER SCIENCE SERIES B | 2004年 / 46卷 / 5-6期

关键词：

D O I：

暂无

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

At 70degreesC, [bis(triphenylphosphino)(3,6-di-tert-butylbenzosemiquinone-1,2)copper(I)] efficiently inhibits AIBN-initiated polymerizations of styrene and butyl methacrylate. After the end of the induction period, thermal (95, 125degreesC) and photoinduced (25degreesC) polymerization of styrene exhibit features typical of pseudoliving radical polymerization, namely, a linear relation between the polymer molecular mass and conversion in the first case and M-w/M-n = 1.32 in the second. Schemes of controlled chain propagation are suggested.

引用

页码：154 / 158

页数：5

共 50 条

[41] LIVING CATIONIC POLYMERIZATION OF STYRENE BY THE BIFUNCTIONAL INITIATING SYSTEM 1,4-BIS(1-CHLOROETHYL)BENZENE SNCL4 IN THE PRESENCE OF 2,6-DI-TERT-BUTYLPYRIDINE
KWON, OS
GHO, CG
CHOI, BS
CHOI, SK
MACROMOLECULAR CHEMISTRY AND PHYSICS, 1994, 195 (06) : 2187 - 2194
[42] FREE-RADICAL ANNELATION IN THE SYNTHESIS OF BICYCLIC BETA-LACTAMS .6. SYNTHESIS OF TERT-BUTYL 2-BENZYLIDENE-1-CARBAPENAM-3-CARBOXYLATE
BACHI, MD
DEMESMAEKER, A
STEVENARTDEMESMAEKER, N
TETRAHEDRON LETTERS, 1987, 28 (25) : 2887 - 2888
[43] Temperature-dependent redox isomerism via intramolecular electron transfer. Synthesis and properties of Co(dmppz)(2)(3,6-dbq)(2)(dmppz=1,4-dimethylpiperazine; 3,6-dbq=3,6-di-tert-butyl-1,2-quinone)
Jung, OS
Jo, DH
Park, SH
Sohn, YS
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1997, 18 (06) : 628 - 631
[44] Di-tert-butyl 3,6-bis(2-methylphenyl)-1,4-dioxo-1,2,4,5-tetrahydropyrrolo-[3,4-c]pyrrole-2,5-dicarboxylate
Mizuguchi, J
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 : O472 - O473
[45] SYNTHESIS AND ELECTRON-PARAMAGNETIC-RES INVESTIGATION OF NEW COORDINATION-COMPOUNDS WITH FREE-RADICAL PHENOXYL LIGANDS BASED ON N-(3,5-DI-TERT-BUTYL-2-HYDROXYPHENYL)SALICYLALDIMINE
IVAKHNENKO, EP
LYUBCHENKO, SN
KOGAN, VA
OLEKHNOVICH, LP
PROKOFEV, AI
ZHURNAL OBSHCHEI KHIMII, 1986, 56 (04): : 869 - 872
[46] Synthesis of 1,2-bis(di-tert-butylphosphino)ethane (dtbpe) complexes of nickel:: radical coupling and reduction reactions promoted by the nickel(I) dimer [(dtbpe)NiCl]2
Mindiola, DJ
Waterman, R
Jenkins, DM
Hillhouse, GL
INORGANICA CHIMICA ACTA, 2003, 345 : 299 - 308
[47] Spectroscopic studies on bis(3,5-di-t-butyl-1,2-benzoquinone 1-oximato)copper(II) and its mixed-ligand complexes.: Copper(II)-radical ferromagnetic coupling
Kasumov, VT
Tas, E
Yakar, Y
Köksal, F
Köseoglu, R
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2002, 57 (05): : 495 - 502
[48] Spectroscopic studies on bis(3,5-di-t-butyl-1,2-benzoquinone 1-oximato)copper(II) and its mixed-ligand complexes. Copper(II)-radical ferromagnetic coupling
Kasumov, Veli T.
Tas¸, Es¸ref
Yakar, Yasin
Köksal, Fevzi
Kös¸oeoglu, Rahmi
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2002, 57 (05): : 495 - 502
[49] CATECHOL OXIDATIONS - CHARACTERIZATION OF METAL-COMPLEXES OF 3,5-DI-TERT-BUTYL-1,2-QUINONE 1-(2-HYDROXY-3,5-DI-TERT-BUTYLPHENYL)IMINE FORMED BY AERIAL OXIDATION OF 3,5-DI-TERT-BUTYLCATECHOL IN PRESENCE OF AMMONIA AND DIVALENT METAL-IONS
GIRGIS, AY
BALCH, AL
INORGANIC CHEMISTRY, 1975, 14 (11) : 2724 - 2727
[50] catena-Poly[[[(triphenylphosphane)copper(I)]-di-μ-iodido-[(triphenylphosphane)copper(I)]-μ-[3,6-bis(4-pyridyl)-1,2,4,5-tetrazine]] acetonitrile disolvate]
Zhang, Jinfang
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M1480 - U1347

← 1 2 3 4 5 →