Silver-Catalyzed anti-Markovnikov Hydroboration of C-C Multiple Bonds

被引：56

作者：

Wang, Yan ^{[1
,2
]}

Guan, Rui ^{[1
,2
]}

Sivaguru, Paramasivam ^{[2
]}

Gong, Xuefeng ^{[2
]}

Bi, Xihe ^{[2
]}

机构：

[1] Changchun Univ Technol, Sch Chem & Life Sci, Changchun 130012, Jilin, Peoples R China

[2] Northeast Normal Univ, Dept Chem, Jilin Prov Key Lab Organ Funct Mol Design & Synth, Changchun 130024, Jilin, Peoples R China

来源：

ORGANIC LETTERS | 2019年 / 21卷 / 11期

关键词：

ASYMMETRIC HYDROBORATION; SELECTIVE HYDROBORATION; ALKENE HYDROBORATION; COUPLING REACTIONS; COBALT CATALYSTS; IRON; COMPLEXES; ALKYNES; ORGANOBORANES; INSERTION;

D O I：

10.1021/acs.orglett.9b01217

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple silver salt (AgOAc)-catalyzed anti-Markov-nikov-selective hydroboration of alkenes, 1,3-dienes, and alkynes with pinacolborane (HBpin) has been described. This strategy provides an efficient and practical method to access various alkyl-, allyl-, and (E)-alkenylboronate esters in good to excellent yields with regio- and stereoselectivity under ligand- and base-free conditions.

引用

页码：4035 / 4038

页数：4

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