Globally accurate theory of structure and thermodynamics for soft-matter liquids

被引:14
|
作者
Pini, D
Stell, G [1 ]
机构
[1] SUNY Stony Brook, Dept Chem, Stony Brook, NY 11794 USA
[2] Univ Milan, INFM, I-20133 Milan, Italy
[3] Univ Milan, Dipartimento Fis, I-20133 Milan, Italy
关键词
coexistence curve; lattice gas; Ornstein-Zernike theory; thermodynamic consistency; Yukawa fluid;
D O I
10.1016/S0378-4371(02)00504-6
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Standard statistical mechanical approximations (e.g. mean-field approximations) for pair-correlation functions of strongly interacting systems that yield adequate thermodynamics away from critical points typically break down badly in critical regions. The self-consistent Ornstein-Zemike approximation (SCOZA) transcends this difficulty, yielding globally accurate Structure and thermodynamics. The SCOZA has been applied successfully to a variety of Hamiltonian models and the result will be briefly summarized. We end with a progress report on the applications of the SCOZA to some soft-matter systems. (C) 2002 Published by Elsevier Science B.V.
引用
收藏
页码:270 / 278
页数:9
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