Synthesis of Planar Chiral Ferrocenes by Transition-Metal-Catalyzed Enantioselective C-H Activation

被引：105

作者：

Zhu, Dao-Yong ^{[1
]}

Chen, Ping ^{[2
]}

Xia, Ji-Bao ^{[1
]}

机构：

[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, Suzhou Res Inst LICP, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China

[2] Nanyang Inst Technol, Dept Biochem Engn, Nanyang 473004, Peoples R China

来源：

CHEMCATCHEM | 2016年 / 8卷 / 01期

关键词：

C-H activation; enantioselective catalysis; ferrocenes; planar chirality; transition-metal catalysis; ASYMMETRIC-SYNTHESIS; BOND ACTIVATION; QUATERNARY STEREOCENTERS; KINETIC RESOLUTION; ORTHO-LITHIATION; LIGANDS; DERIVATIVES; SILYLATION; ALKYLATION; C(SP(2))-H;

D O I：

10.1002/cctc.201500895

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This minireview focuses on recent advancements in the synthesis of planar chiral ferrocenes by means of transition-metal-catalyzed enantioselective C-H activation. Enantioenriched planar chiral ferrocenes are synthesized through simple straightforward asymmetric carbon-carbon or carbon-hetero-atom bond-formation reactions. In these reports, site selectivity of ferrocene C-H activation is controlled by two strategies, coordination direction and intramolecular cyclization. Herein the significance of these results is summarized.

引用

页码：68 / 73

页数：6

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