Two type skeleton heterobimetallic trinuclear Cu-Mo-S clusters containing closo carborane diphosphine ligand 1,2-bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane

被引：9
|
作者：
Dou, Jianmin [1 ]
Zhang, Daopeng [1 ]
Li, Dacheng [1 ]
Wang, Daqi [1 ]
机构：
[1] Liaocheng Univ, Dept Chem, Liaocheng 252059, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2006年 / 9卷 / 11期
基金：
中国国家自然科学基金;
关键词：
synthesis and characterization; crystal structure; Cu-Mo-S cluster; 1,2-bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane;
D O I：
10.1016/j.inoche.2006.07.006
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The carborane skeleton was introduced into the heterometallic sulfide cluster cores. Two heterobimetallic trinuclear Cu-Mo-S clusters with linear or butterfly-shaped skeleton containing 1,2-bis(diphenylphosphino)-1,2-dicarba-closo-dodecaborane have been synthesized by the reactions of (NH4)(2)MoS4 or (NH4)(2)MoOS3, CuSCN with 1,2-(PPh2)(2)-1,2-C2B10H10 (L) in dichloromethane and characterized by elemental analysis, FT-IR, UV/Visible, H-1 and C-13 NMR spectroscopy and X-ray structure determination. (C) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：1099 / 1102
页数：4
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