Three-phase Boundary Length Evaluation in Modeled Sintered Composite Solid Oxide Fuel Cell Electrodes

被引:2
|
作者
Metcalfe, C. [1 ]
Kesler, O. [1 ]
Rivard, T. [2 ]
Gitzhofer, F. [2 ]
Abatzoglou, N. [2 ]
机构
[1] Univ Toronto, Dept Mech & Ind Engn, Toronto, ON M5S 3G8, Canada
[2] Univ Sherbrooke, Dept Chem Engn, Quebec City, PQ J1K 2R1, Canada
来源
SOLID OXIDE FUEL CELLS 11 (SOFC-XI) | 2009年 / 25卷 / 02期
关键词
FUNCTIONALLY GRADED CATHODES; RECONSTRUCTION; FABRICATION;
D O I
10.1149/1.3205647
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A numerical methodology for evaluating the three-phase boundary length in sintered composite electrode layers is developed. Three dimensional models of sintered composite electrodes are generated for which the mean particle diameter, composition, and total porosity may be specified as input parameters. Tomographic methods are used to reconstruct the modeled electrode and the percolation for each phase is evaluated. The connected three-phase boundary length is calculated for a range of electrode designs.
引用
收藏
页码:1185 / 1194
页数:10
相关论文
共 50 条
  • [21] The Orientation Distributions of Lines, Surfaces, and Interfaces around Three-Phase Boundaries in Solid Oxide Fuel Cell Cathodes
    Dillon, Shen J.
    Helmick, Lam
    Miller, Herbert M.
    Wilson, Lane
    Gemman, Randall
    Petrova, Rumyana V.
    Barmak, Katayun
    Rohrer, Gregory S.
    Salvador, Paul A.
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2011, 94 (11) : 4045 - 4051
  • [22] Fluorine-Free Pt Nanocomposites for Three-Phase Interfaces in Fuel Cell Electrodes
    Dru, Delphine
    Baranton, Steve
    Bigarre, Janick
    Buvat, Pierrick
    Coutanceau, Christophe
    ACS CATALYSIS, 2016, 6 (10): : 6993 - 7001
  • [23] Characteristics of three-phase fluidized-bed electrodes for an alkaline fuel cell cathode
    Matsuno, Y
    Suzawa, K
    Tsutsumi, A
    Yoshida, K
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 1996, 21 (03) : 195 - 199
  • [24] Computation of TPB length, surface area and pore size from numerical reconstruction of composite solid oxide fuel cell electrodes
    Kenney, Ben
    Valdmanis, Mikelis
    Baker, Craig
    Pharoah, J. G.
    Karan, Kunal
    JOURNAL OF POWER SOURCES, 2009, 189 (02) : 1051 - 1059
  • [25] One-step fabrication of composite nanofibers for solid oxide fuel cell electrodes
    Ahn, Minwoo
    Cho, Jiung
    Lee, Wonyoung
    JOURNAL OF POWER SOURCES, 2019, 434
  • [26] Electrospun composite nanofibers for intermediate-temperature solid oxide fuel cell electrodes
    Ahn, Minwoo
    Han, Seungwoo
    Lee, Jongseo
    Lee, Wonyoung
    CERAMICS INTERNATIONAL, 2020, 46 (05) : 6006 - 6011
  • [27] Phase Stability of Perovskite Oxide Electrodes under Operating Condition in Solid Oxide Fuel Cell
    Lee, Jinsil
    Shin, Yonghun
    Kim, Taeyun
    Choi, Wooseon
    Jung, Min-Hyoung
    Kim, Young-Min
    Yoon, Kyung Joong
    Jeong, Hu Young
    Lee, Donghwa
    Joo, Jong Hoon
    CHEMISTRY OF MATERIALS, 2024, 36 (06) : 2933 - 2943
  • [28] Fuel cell model for three-phase inverter
    Younis, M. A. A.
    Rahim, N. A.
    Mekhilef, S.
    FIRST INTERNATIONAL POWER & ENERGY CONFERENCE (PECON 2006), PROCEEDINGS, 2006, : 399 - 404
  • [29] Film percolation for composite electrodes of solid oxide fuel cells
    Zhang, Yanxiang
    Xia, Changrong
    ELECTROCHIMICA ACTA, 2011, 56 (13) : 4763 - 4769
  • [30] Polarization Characteristics and Microstructural Changes of Solid Oxide Fuel Cell and Solid Oxide Electrolysis Cell Fuel Electrodes
    Shimura, Takaaki
    Jiao, Zhenjun
    Shikazono, Naoki
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2017, 164 (12) : F1158 - F1164