O-Ethyl-S-(1,2,2,2-Tetrafluoroethyl)-Dithiocarbonate: A Convenient Reagent for the Generation and Capture of 1,2,2,2-Tetrafluoroethyl Radicals

被引：2

作者：

Clemente-Tejeda, David ^{[1
]}

Zard, Samir Z. ^{[1
]}

机构：

[1] CNRS, UMR 7652, Ecole Polytech, Synth Organ Lab, F-91128 Palaiseau, France

来源：

SYNLETT | 2016年 / 27卷 / 01期

关键词：

organofluorine; xanthates; alkenes; radical addition; indolines; CHLORO-TRIFLUOROMETHYL DERIVATIVES; ALPHA-TRIFLUOROMETHYLAMINES; FLUORINE; CONVERGENT; ROUTE; SUBSTITUTION; CHEMISTRY;

D O I：

10.1055/s-0035-1560539

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of a new fluorinated reagent O-ethyl S-(1,2,2,2-tetrafluoroethyl) carbonodithioate (xanthate) and its use for the generation and capture of the hitherto unexplored 1,2,2,2-tetrafluoroethyl radicals is described. This reagent allows the convenient introduction of the rare CF3CHF motif onto various olefinic substrates with a high functional-group tolerance.

引用

页码：136 / 140

页数：5

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