O-Ethyl-S-(1,2,2,2-Tetrafluoroethyl)-Dithiocarbonate: A Convenient Reagent for the Generation and Capture of 1,2,2,2-Tetrafluoroethyl Radicals

被引：2
|
作者：
Clemente-Tejeda, David [1 ]
Zard, Samir Z. [1 ]
机构：
[1] CNRS, UMR 7652, Ecole Polytech, Synth Organ Lab, F-91128 Palaiseau, France
来源：
SYNLETT | 2016年 / 27卷 / 01期
关键词：
organofluorine; xanthates; alkenes; radical addition; indolines; CHLORO-TRIFLUOROMETHYL DERIVATIVES; ALPHA-TRIFLUOROMETHYLAMINES; FLUORINE; CONVERGENT; ROUTE; SUBSTITUTION; CHEMISTRY;
D O I：
10.1055/s-0035-1560539
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The synthesis of a new fluorinated reagent O-ethyl S-(1,2,2,2-tetrafluoroethyl) carbonodithioate (xanthate) and its use for the generation and capture of the hitherto unexplored 1,2,2,2-tetrafluoroethyl radicals is described. This reagent allows the convenient introduction of the rare CF3CHF motif onto various olefinic substrates with a high functional-group tolerance.
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页码：136 / 140
页数：5
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