Solubility of krypton in solutions of potassium bromide and tetra-n-butylammonium in isotopomers of methanol at various temperatures

被引:0
|
作者
Abrosimov, VK
Ivanov, EV
Ivanova, NG
机构
[1] Russian Acad Sci, Inst Chem Solut, Ivanovo 153045, Russia
[2] Ivanovo Power Engn Univ, Ivanovo, Russia
来源
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY | 2004年 / 78卷 / 05期
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中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The solubility of krypton in solutions of KBr and n-Bu4NBr in CH3OH, CH3OD, and CD3OH (isotopomers of methanol) at a partial gas pressure of 101325 Pa, various concentrations of the solutes, and temperatures of 278, 288, 298, 308, and 318 K was studied using microgasometry. Based on the solubility data obtained, the Sechenov salt effect standard coefficients and the thermodynamic parameters of the Kr-electrolyte pair interaction were examined within the framework of the Ben-Naim and McMillan-Mayer theories.
引用
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页码:741 / 746
页数:6
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