A Flexible and High-Voltage Internal Tandem Supercapacitor Based on Graphene-Based Porous Materials with Ultrahigh Energy Density

被引：58
|
作者：
Zhang, Fan [1 ,2 ]
Lu, Yanhong [1 ,2 ]
Yang, Xi [1 ,2 ]
Zhang, Long [1 ,2 ]
Zhang, Tengfei [1 ,2 ]
Leng, Kai [1 ,2 ]
Wu, Yingpeng [1 ,2 ]
Huang, Yi [1 ,2 ]
Ma, Yanfeng [1 ,2 ]
Chen, Yongsheng [1 ,2 ]
机构：
[1] Nankai Univ, Key Lab Funct Polymer Mat, Tianjin 300071, Peoples R China
[2] Nankai Univ, Ctr Nanoscale Sci & Technol, Inst Polymer Chem, Coll Chem, Tianjin 300071, Peoples R China
来源：
SMALL | 2014年 / 10卷 / 11期
关键词：
FUEL-CELL STACKS; ELECTRODE MATERIALS; AQUEOUS SUPERCAPACITORS; CARBON MATERIALS; SURFACE-AREA; IONIC LIQUID; OXIDE SHEETS; PORE-SIZE; PERFORMANCE; FABRICATION;
D O I：
10.1002/smll.201303240
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Pursuing higher working voltage and packaged energy density, an internal tandem supercapacitor has been successfully designed and fabricated based on graphene-based porous carbon hybrid material. Compared with the packaged energy density of 27.2 Wh kg(cell)(-1) and working voltage of 3.5 V using EMIMBF4 electrolyte for the conventional single-cell supercapacitor, the internal tandem device with the same material achieves a much higher working voltage of 7 V as well as a significantly improved energy density of 36.3 Wh kg(cell)(-1) (increased by 33%), which is also about 7 times of that of the state-of-art commercial supercapacitors. A flexible internal tandem device is also designed and fabricated and demonstrated similar excellent performance.
引用
收藏
页码：2285 / 2292
页数：8
相关论文
共 50 条
  • [41] High-energy-density flexible graphene-based supercapacitors enabled by atypical hydroquinone dimethyl ether
    Wang, Jian
    Wang, Zhenquan
    Li, Zhiming
    Liu, Naxing
    Luo, Yang
    Chu, Yuxiao
    Jiang, Long
    Zhao, Fu-Gang
    Zhang, Kai
    Liu, Xunshan
    Shen, Yongmiao
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2023, 648 : 231 - 241
  • [42] Research Progress of Graphene-Based Materials on Flexible Supercapacitors
    Du, Yongquan
    Xiao, Peng
    Yuan, Jian
    Chen, Jianwen
    COATINGS, 2020, 10 (09)
  • [43] Charge transport mechanism in reduced graphene oxide/polypyrrole based ultrahigh energy density supercapacitor
    Abu Jahid Akhtar
    Shubhankar Mishra
    Sudip Kumar Saha
    Journal of Materials Science: Materials in Electronics, 2020, 31 : 11637 - 11645
  • [44] Charge transport mechanism in reduced graphene oxide/polypyrrole based ultrahigh energy density supercapacitor
    Akhtar, Abu Jahid
    Mishra, Shubhankar
    Saha, Sudip Kumar
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2020, 31 (14) : 11637 - 11645
  • [45] Direct synthesis of graphene-based hybrid films as flexible supercapacitor electrodes
    Jia, Yunming
    Zhou, Lan
    Shao, Jianzhong
    SYNTHETIC METALS, 2018, 244 : 99 - 105
  • [46] Graphene-based membrane and porous materials for gas separation
    Jiang, De-en
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 246
  • [47] Graphene-based materials for energy conversion applications
    Amollo T.A.
    Nyamori V.O.
    SPR Nanoscience, 2020, 6 : 150 - 173
  • [48] Binary ionic liquid electrolyte design for ultrahigh-energy density graphene-based supercapacitors
    Wong, Shao Ing
    Lin, Han
    Ma, Tianyi
    Sunarso, Jaka
    Wong, Basil T.
    Jia, Baohua
    MATERIALS REPORTS: ENERGY, 2022, 2 (02):
  • [49] Tuning the capacitance of graphene-based materials as negative electrode materials for supercapacitor applications
    Azman, Nur Hawa Nabilah
    Lim, Xiang Chuan
    Sulaiman, Yusran
    DIAMOND AND RELATED MATERIALS, 2025, 152
  • [50] Flexible Phase Change Materials with High Energy Storage Density Based on Porous Carbon Fibers
    Peng, Xiangqin
    Chen, Lei
    Li, Bohong
    Tang, Zhe
    Jia, Yifan
    Zhang, Zhenyu Jason
    Yu, Qianqian
    Wang, LinGe
    POLYMERS, 2024, 16 (24)
12345