Templated synthesis of Cr2O3 material for energetic composites with high performance

被引:8
|
作者
Gibot, Pierre [1 ]
机构
[1] Inst Franco Allernand Rech St Louis ISL, CNRS ISL UNISTRA UMR 3208, Lab Nanomat Syst Solicitat Extremes NS3E, F-68301 St Louis, France
关键词
Cr2O3; nanomaterial; Fumed silica; Template synthesis; Energetic composites; CHROMIUM-OXIDE; NANOCRYSTALLINE CR2O3; REACTION PROPAGATION; NANOPARTICLES; COMBUSTION; MECHANISM; AL/MOO3;
D O I
10.1016/j.solidstatesciences.2019.05.014
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A facile templated approach has been developed for the synthesis of Cr2O3 chromium (III) oxide material with low particle size and tunable textural properties. While chromium nitrate nonahydrate was used as chromium source, fumed silica was selected as template. The Cr2O3 powders were characterized by X-ray Diffraction, High Resolution Transmission Electron Microcopy and nitrogen physisorption. Results showed that the particles size and the textural properties of the as-synthesized Cr(2)O(3)materials depend on the fumed silica/Cr-precursor weight ratio. Used in energetic composites, like nanothermites implementing metal and oxide nanopowders, the silicatemplated Cr2O3 material leads both to make easier the ignition and to increase the combustion velocity of the mixture.
引用
收藏
页码:162 / 167
页数:6
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