Relation between microstructure, physical properties and martensitic transformations in Ni-rich Ni-Ti shape memory alloys

被引:0
|
作者
Wassermann, EF [1 ]
Somsen, C [1 ]
Kästner, J [1 ]
Schryvers, D [1 ]
Kompatscher, M [1 ]
Kostorz, G [1 ]
机构
[1] Gerhard Mercator Univ, Tieftemp Phys, D-47048 Duisburg, Germany
来源
PRICM 4: FORTH PACIFIC RIM INTERNATIONAL CONFERENCE ON ADVANCED MATERIALS AND PROCESSING, VOLS I AND II | 2001年
关键词
martensitic transformations; nickel titanium (NiTi) shape memory alloys; nickel-titanium precipitates (Ni4Ti3); B19 ' martensite and R-phase precursors;
D O I
暂无
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We investigated NixTi180-x alloys with 51 less than or equal to x less than or equal to 54 at% Ni, quenched from 1000degreesC (B2 phase region). SANS measurements reveal the presence of precipitates on a length scale from 0.9nm (x = 51.5) to 1.32nm (x = 54), increasing in volume fraction from 0.3 % to 6 %. Diffuse diffraction spots in TEM identify the precipitates as Ni4Ti3, HREM shows their coherence. Additional reflections for x = 52 can be related to precursors of B19' martensite or R-phase, respectively. We assume that the strain fields of the Ni4Ti3 precipitates are the regions of R-phase formation, i.e. the precipitates trigger the R-martensite, responsible for the SME. The high value of the absolute resistivity (rho similar to 100muOmegacm) and the increase of rho(T)up to 40% between R.T. and 4.2K very likely originate from strain fields due to Ni4Ti3, precipitates in the early stage of formation.
引用
收藏
页码:1791 / 1794
页数:4
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