Effect of oxygen partial pressure on the structural and optical properties of dc reactive magnetron sputtered molybdenum oxide films

Molybdenum oxide films (MoO(3)) were deposited on glass and crystalline silicon substrates by sputtering of molybdenum target under various oxygen partial pressures in the range 8 x 10(-5)-8 x 10(-4) mbar and at a fixed substrate temperature of 473 K employing dc magnetron sputtering technique. The influence of oxygen partial pressure on the composition stoichiometry, chemical binding configuration, crystallographic structure and electrical and optical properties was systematically Studied. X-ray photoelectron spectra of the films formed at 8 x 10(-5) mbar showed the presence of Mo(6+) and Mo(5+) oxidation states of MoO(3) and MoO(3-x). The films deposited at oxygen partial pressure of 2 x 10(-4) mbar showed Mo(6+) oxidation state indicating the films were nearly stoichiometric. It was also confirmed by the Fourier transform infrared spectroscopic studies. X-ray diffraction studies revealed that the films formed at oxygen partial pressure of 2 x 10(-4) mbar showed the presence of (0 k 0) reflections indicated the layered structure of alpha-phase MoO(3). The electrical conductivity of the films decreased from 3.6 x 10(-5) to 1.6 x 10(-6) Omega(-1) cm(-1), the optical band gap of the films increased from 2.93 to 3.26 eV and the refractive index increased from 2.02 to 2.13 with the increase of oxygen partial pressure frorn 8 x 10(-5) to 8 x 10(-4) mbar, respectively. (C) 2009 Elsevier B.V. All rights reserved.