nBu4NI-Catalyzed oxidative imidation of ketones with imides: synthesis of α-amino ketones

被引:105
|
作者
Lv, Yunhe [1 ]
Li, Yan [1 ]
Xiong, Tao [1 ]
Lu, Yu [1 ]
Liu, Qun [1 ]
Zhang, Qian [1 ]
机构
[1] NE Normal Univ, Dept Chem, Changchun 130024, Peoples R China
关键词
C-H AMINATION; AMIDATION; ACETOPHENONES; DERIVATIVES; CATALYSIS; ALDEHYDES; REAGENTS;
D O I
10.1039/c3cc48887j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
nBu(4)NI-Catalyzed oxidative imidation of ketones and imides for the synthesis of a-amino ketones were realized for the first time. The methodology is characterized by its wide substrate scope even for acetone with readily available phthalimide, saccharin and succinimide, which opens a new pathway for direct imidation of ketones.
引用
收藏
页码:2367 / 2369
页数:3
相关论文
共 50 条
  • [31] Synthesis of chiral cyclic β-amino ketones by Ru-catalyzed asymmetric hydrogenation
    Huang, Kexuan
    Guan, Zheng-Hui
    Zhang, Xumu
    TETRAHEDRON LETTERS, 2014, 55 (10) : 1686 - 1688
  • [32] Recent advances in the synthesis of α-amino ketones
    Allen, Lewis A. T.
    Raclea, Robert-Cristian
    Natho, Philipp
    Parsons, Philip J.
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2021, 19 (03) : 498 - 513
  • [33] Synthesis of β-amino ketones by iridium(III)-catalyzed direct-Mannich reaction
    Sueki, Shunsuke
    Igarashi, Takeyuki
    Nakajima, Takayuki
    Shimizu, Isao
    CHEMISTRY LETTERS, 2006, 35 (06) : 682 - 683
  • [34] An iodine(III) mediated oxidative rearrangement of enamines: efficient synthesis of α-amino ketones
    Yadagiri, Dongari
    Anbarasan, Pazhamalai
    CHEMICAL COMMUNICATIONS, 2015, 51 (75) : 14203 - 14206
  • [35] Cobalt(III)-Catalyzed and Dimethyl Sulfoxide-Involved Cross-Coupling of Ketones and Amides for Direct Synthesis of β-Amino Ketones
    Xu, Xuefeng
    Zhou, Zhi
    Wang, Zhipin
    Ma, Xinna
    Chen, Xin
    Zhang, Xu
    Yu, Xiyong
    Yi, Wei
    ADVANCED SYNTHESIS & CATALYSIS, 2019, 361 (18) : 4278 - 4285
  • [36] Rhodium-catalyzed Asymmetric Hydrogenation of -Dehydroamino Ketones: A General Approach to Chiral -amino Ketones
    Gao, Wenchao
    Wang, Qingli
    Xie, Yun
    Lv, Hui
    Zhang, Xumu
    CHEMISTRY-AN ASIAN JOURNAL, 2016, 11 (02) : 231 - 233
  • [37] Palladium-catalyzed tandem oxidative annulation of α-amino ketones leading to 2-aroylindoles
    Jiang, Tao-Shan
    Dai, Long
    Zhou, Yuhui
    Zhang, Xiuli
    TETRAHEDRON, 2020, 76 (07)
  • [38] Cu-Catalyzed Pyridine Synthesis via Oxidative Annulation of Cyclic Ketones with Propargylamine
    Sotnik, Svitlana O.
    Subota, Andrii, I
    Kliuchynskyi, Anton Y.
    Yehorov, Dmytro, V
    Lytvynenko, Anton S.
    Rozhenko, Alexander B.
    Kolotilov, Sergey, V
    Ryabukhin, Sergey, V
    Volochnyuk, Dmitriy M.
    JOURNAL OF ORGANIC CHEMISTRY, 2021, 86 (11): : 7315 - 7325
  • [39] Synthesis of α,β-unsaturated ketones using an oxidative Pd-catalyzed cyclopropanol ring opening
    Merrill, Darcy M.
    Funk, Timothy W.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
  • [40] Amino ketones II The synthesis of alpha,beta-diamines from alpha-amino ketones
    Cromwell, NH
    Hoeksema, H
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1944, 66 : 870 - 871