Transition metal catalyzed ring opening reactions of 2-phenyl-3-vinyl substituted 2H-azirines

被引：57

作者：

Padwa, A ^{[1
]}

Stengel, T ^{[1
]}

机构：

[1] Emory Univ, Dept Chem, Atlanta, GA 30322 USA

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 31期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/j.tetlet.2004.06.046

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of 2-phenyl-3-vinyl-substituted 2H-azirines with Grubbs' catalyst induces a clean rearrangement and affords products derived from carbon-nitrogen bond cleavage of the 2H-azirine ring. However, when the reaction was carried Out using Wilkinson's catalyst in an alcoholic solvent, the only product obtained in high yield corresponded to an alpha,beta-tinsaturated oxime. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：5991 / 5993

页数：3

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