Nickel-catalyzed product-controllable amidation and imidation of sp3 C-H bonds in substituted toluenes with sulfonamides

被引：17
|
作者：
Li, Ze-lin [1 ]
Jin, Li-kun [1 ]
Cai, Chun [1 ]
机构：
[1] Nanjing Univ Sci & Technol, Chem Engn Coll, 200 Xiao Ling Wei St, Nanjing, Jiangsu, Peoples R China
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2017年 / 15卷 / 06期
关键词：
RUTHENIUM PORPHYRINS; AEROBIC OXIDATION; N-ALKYLATION; AMINATION; AMINES; ALCOHOLS; AMIDES; FUNCTIONALIZATION; AZIRIDINATION; HYDROCARBONS;
D O I：
10.1039/c7ob00022g
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A nickel-catalyzed product-controllable imidation and amidation of sp(3) C-H bonds in substituted toluenes with sulfonamides were developed. Based on the change of the reaction time and atmosphere from N-2 to O-2, this reaction proceeded in high yields and excellent selectivity under different conditions. Mechanistic details were also described.
引用
收藏
页码：1317 / 1320
页数：4
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