Synthesis of the C1-C16 fragment of ionomycin using a neutral (η3-allyl)iron complex

被引：15

作者：

Cooksey, John P. ^{[1
]}

Kocienski, Philip J. ^{[1
]}

Li, Ying-fa ^{[1
]}

Schunk, Stefan ^{[1
]}

Snaddon, Thomas N. ^{[1
]}

机构：

[1] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2006年 / 4卷 / 17期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1039/b606262h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Key steps in the synthesis of the C1 - C16 polyketide fragment of ionomycin were the nucleophilic addition of an organocuprate to a neutral (eta(3)-allyl) iron complex and the construction of a beta-diketone moiety by the Rh-catalysed rearrangement of an alpha-diazo-beta-hydroxyketone.

引用

页码：3325 / 3336

页数：12

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