Enantiospecific total syntheses of meroterpenoids (-)-F1839-I and (-)-corallidictyals B and D

被引：17

作者：

Dethe, Dattatraya H. ^{[1
]}

Dherange, Balu D. ^{[1
]}

Ali, Saghir ^{[1
]}

Parsutkar, Mahesh M. ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2017年 / 15卷 / 01期

关键词：

FUNGUS STACHYBOTRYS-CHARTARUM; COMPLEMENT INHIBITOR K-76; STRUCTURE REVISION; PHENYLSPIRODRIMANES; CORALLIPHAGUM; METABOLITES; ACID;

D O I：

10.1039/c6ob02322c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Enantiospecific total syntheses of spiromeroterpenoid natural products (-)-F1839-I and (-)-corallidictyals B and D were achieved using the environmentally benign and highly atom economical Lewis acid catalysed Friedel-Crafts reaction and a highly regio- and stereoselective spirocyclic C-O bond formation reaction.

引用

页码：65 / 68

页数：4

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