Enantiospecific total syntheses of meroterpenoids (-)-F1839-I and (-)-corallidictyals B and D

被引:17
|
作者
Dethe, Dattatraya H. [1 ]
Dherange, Balu D. [1 ]
Ali, Saghir [1 ]
Parsutkar, Mahesh M. [1 ]
机构
[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India
关键词
FUNGUS STACHYBOTRYS-CHARTARUM; COMPLEMENT INHIBITOR K-76; STRUCTURE REVISION; PHENYLSPIRODRIMANES; CORALLIPHAGUM; METABOLITES; ACID;
D O I
10.1039/c6ob02322c
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Enantiospecific total syntheses of spiromeroterpenoid natural products (-)-F1839-I and (-)-corallidictyals B and D were achieved using the environmentally benign and highly atom economical Lewis acid catalysed Friedel-Crafts reaction and a highly regio- and stereoselective spirocyclic C-O bond formation reaction.
引用
收藏
页码:65 / 68
页数:4
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