Synthesis of boron imidazolate frameworks with cobalt clusters for efficient visible-light driven CO2 reduction

被引：42
|
作者：
Hong, Qin-Long [1 ]
Zhang, Hai-Xia [1 ]
Zhang, Jian [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
来源：
JOURNAL OF MATERIALS CHEMISTRY A | 2019年 / 7卷 / 29期
关键词：
METAL-ORGANIC FRAMEWORKS; PHOTOCATALYTIC CONVERSION; DESIGN;
D O I：
10.1039/c9ta04842a
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Photocatalytic conversion of CO2 into chemical fuel is highly appealing to reduce the atmospheric CO2 level and fulfil the future energy demand. Here, we demonstrate a crystalline porous boron imidazolate framework (BIF-101) exhibiting trinuclear cobalt clusters as connecting nodes and preferable CO2 capture. Furthermore, it exhibits highly efficient photocatalytic performance for CO2 reduction with a CO evolution rate up to 5830 mu mol g(-1) h(-1) under visible-light irradiation. The electron transfer from a ruthenium-based photosensitizer to BIF-101 is studied via fluorescence emission quenching and electrochemistry experiments.
引用
收藏
页码：17272 / 17276
页数：5
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