Multiple threading of a triple-calix[6]arene host

被引：3

作者：

Iuliano, Veronica ^{[1
]}

Ciao, Roberta ^{[1
]}

Vignola, Emanuele ^{[1
]}

Talotta, Carmen ^{[1
]}

Iannece, Patrizia ^{[1
]}

De Rosa, Margherita ^{[1
]}

Soriente, Annunziata ^{[1
]}

Gaeta, Carmine ^{[1
]}

Neri, Placido ^{[1
]}

机构：

[1] Univ Salerno, Lab Supramol Chem, Dipartimento Chim & Biol A Zambelli, Via Giovanni Paolo II 132, I-84084 Salerno, Italy

来源：

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2019年 / 15卷

关键词：

calixarene; multiple-threading; pseudo[n]rotaxane; stereoisomers; PSEUDOROTAXANE; FUNCTIONALIZATION; COMPLEXATION; RECOGNITION; CAVITY; WHEEL; UNITS; AXLE;

D O I：

10.3762/bjoc.15.207

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of the triple-calix[6]arene derivative 6 in which three calix[6]arene macrocycles are linked to a central 1,3,5-trimethylbenzene moiety is reported. Derivative 6 is able to give multiple-threading processes in the presence of dialkylammonium axles. The formation of pseudo[2]rotaxane, pseudo [3]rotaxane, and pseudo [4]rotaxane by threading one, two, and three, respectively, calix-wheels of 6 has been studied by 1D and 2D NMR, DOSY, and ESI-FT-ICR MS/MS experiments. The use of a directional alkylbenzylammonium axle led to the stereoselective formation of endo-alkyl pseudo [n]rotaxane stereoisomers.

引用

页码：2092 / 2104

页数：13

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