SRN1 and stille reactions:: A new synthetic strategy

被引：0
|
作者：
Corsico, EF [1 ]
Rossi, RA [1 ]
机构：
[1] Univ Nacl Cordoba, INFIQC, Dept Quim Organ, Fac Ciencias Quim, RA-5000 Cordoba, Argentina
来源：
MOLECULES | 2000年 / 5卷 / 03期
关键词：
D O I：
10.3390/50300431
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
The photostimulated reaction of Me3Sn- ion with mono, di and trichloro arenes in liquid ammonia gave very good yields of stannanes by the S(RN)1 mechanism. These products reacted by a palladium-catalized cross coupling reaction with halobenzenes to give phenylated products also in very goods yields. Similar yields can be obtained in one-pot reactions.
引用
收藏
页码：431 / 432
页数：2
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