Structure studies of Ni(II) complexes with picolinaldehyde N-oxide thiosemicarbazone

被引：14

作者：

Qing, Yu

Hua, Deng Ji

Gang, Zhu Li

Qing, Zhang Xiu

Dong, Bian He

Hong, Liang

机构：

[1] Guangxi Normal Univ, Coll Chem & Chem Engn, Guilin 541004, Guangxi, Peoples R China

[2] Yulin Teachers Coll, Dept Chem & Chem Engn, Yulin 573000, Guangxi, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2006年 / 794卷 / 1-3期

关键词：

Schiff base; nickel(II) complex; picolinaldehyde N-oxide; thiosemicarbazone; crystal structure;

D O I：

10.1016/j.molstruc.2006.01.036

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two nickel(II) complexes [Ni(HPiotsc)(2)(NO3)(2)] (1), [Ni(Hpiotsc)(2)(NO3)(2)] (.) H2O (2) were synthesized and characterized by single crystal X-ray diffraction, IR, and thermal analyses. The geometry of the nickel(II) atom in two complexes is a distorted octahedron with ONS atoms of two neutral ligands. The antimicrobial activities of complex 1 were evaluated by the MIC (minimum inhibitory concentration) against five bacteria. The six-coordinate complex 1 did not inhibit the growth of the test organisms. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：71 / 76

页数：6

共 50 条

[21] PYRIDINE N-OXIDE AND 4-METHYLPYRIDINE N-OXIDE COMPLEXES WITH ZINC(II) SULPHATE
AHUJA, IS
INDIAN JOURNAL OF CHEMISTRY, 1971, 9 (02): : 173 - &
[22] Photoacoustic powder spectra of Ni(II) and Co(II) complexes with aromatic amine N-oxide ligands
Trabjerg, I
Hansen, T
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1998, 54 (11) : 1715 - 1720
[23] Photoacoustic powder spectra of Ni(II) and Co(II) complexes with aromatic amine N-oxide ligands
Trabjerg, I.
Hansen, T.
Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy, 1998, 54A (11): : 1715 - 1720
[24] ANTIPYRINE AND PYRIDINE N-OXIDE COMPLEXES OF IRON(II)
PRABHAKARAN, CP
PATEL, CC
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1972, 34 (11): : 3485 - +
[25] NEW PLATINUM(II) COMPLEXES WITH PYRIDINE N-OXIDE
KUKUSHKIN, YN
KOTELNIKOV, VP
ROMANYUK, TG
ZHURNAL NEORGANICHESKOI KHIMII, 1978, 23 (03): : 822 - 824
[26] STUDIES ON COMPLEX OF METAL(II) CARBOXYLATES WITH DONOR MOLECULES .2. COMPLEXES OF NI(II) PROPIONATE AND NI(II) NORMAL-BUTYRATE WITH PYRIDINE N-OXIDES, QUINOLINE N-OXIDE AND TRIPHENYLPHOSPHINE OXIDE
KUMAR, N
KACHROO, PL
KANT, R
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1979, 18 (03): : 265 - 266
[27] STRUCTURE OF DICHLOROBIS(PYRIDINE N-OXIDE)ZINC(II)
MCCONNELL, NM
DAY, RO
WOOD, JS
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1986, 42 : 1094 - 1095
[28] COPPER(II) COMPLEXES OF 4-METHYLPYRIDINE N-OXIDE
HERLOCKER, DW
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1972, 34 (01): : 389 - +
[29] TRANSITION-METAL ION COMPLEXES OF THIOSEMICARBAZONES DERIVED FROM 2-ACETYLPYRIDINE N-OXIDE .3. SPECTRAL AND THERMAL STUDIES OF THE METAL-COMPLEXES OF 2-ACETYLPYRIDINE N-OXIDE THIOSEMICARBAZONE
WEST, DX
ALBERT, JN
TRANSITION METAL CHEMISTRY, 1991, 16 (01) : 1 - 4
[30] SPECTROSCOPIC STUDIES ON PYRIDINE N-OXIDE COMPLEXES OF IRON(III)
COTTON, SA
GIBSON, JF
JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (12): : 2105 - &

← 1 2 3 4 5 →