Butane-butylene fraction cracking over modified ZSM-5 zeolite

被引：10
|
作者：
Altynkovich, E. O. [1 ]
Potapenko, O. V. [1 ]
Sorokina, T. P. [1 ]
Doronin, V. P. [1 ]
Gulyaeva, T. I. [1 ]
Talzi, V. P. [1 ]
机构：
[1] Russian Acad Sci, Inst Hydrocarbon Proc, Siberian Branch, Omsk, Russia
来源：
PETROLEUM CHEMISTRY | 2017年 / 57卷 / 03期
关键词：
BBF cracking; ZSM-5; ethylene; propylene; butylenes; CATALYTIC CRACKING; PROPYLENE PRODUCTION; ADSORPTION; 1-BUTENE; HZSM-5; SUPERMICROPORES; TRANSFORMATION; HYDROCARBONS; PROPENE;
D O I：
10.1134/S0965544117010030
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The effect of temperature (530-590A degrees C), weight hourly space velocity (2.5-7.0 h(-1)), and the Si/Al ratio of the ZSM-5 zeolite (30, 55, 80, 300) on the cracking of a butane-butylene fraction containing 85 wt % butylenes has been studied. The HZSM-5 zeolite has been modified with phosphorus. The effect of modification on the catalyst activity in cracking reactions has been studied. The ethylene and propylene yield achieves 38.4 wt % at a degree of conversion of butylenes of 81.5%. The ethylene to propylene ratio is 0.55.
引用
收藏
页码：215 / 221
页数：7
相关论文
共 50 条
  • [31] Catalytic Cracking for Propylene Production over Au Catalyst Supported by External Surface-Modified ZSM-5 Zeolite
    Wu, Lei
    Su, Huijuan
    Sun, Xun
    Sun, Libo
    Zhao, Lijun
    Qi, Caixia
    CATALYSTS, 2022, 12 (04)
  • [32] Catalytic deoxygenation of benzaldehyde over gallium-modified ZSM-5 zeolite
    Ausavasukhi, Artit
    Sooknoi, Tawan
    Resasco, Daniel E.
    JOURNAL OF CATALYSIS, 2009, 268 (01) : 68 - 78
  • [33] Catalytic Cracking of JP-10 on Zeolite ZSM-5
    Xie Wenjie
    Fang Wenjun
    Xing Yan
    Guo Yongsheng
    Lin Ruisen
    ACTA CHIMICA SINICA, 2009, 67 (01) : 6 - 12
  • [34] ZEOLITE ZSM-5
    POLAK, F
    PRZEMYSL CHEMICZNY, 1979, 58 (01): : 8 - 10
  • [35] Hydroformylation of butane-butylene fraction using Co(COOR)(2) catalyst as a precursor
    Vigranenko, YT
    Gavrilova, VM
    Gvozdovskii, GN
    Rybakov, VA
    Kuzmina, GV
    Pavlova, VA
    Bogdanova, LV
    ZHURNAL ORGANICHESKOI KHIMII, 1996, 32 (12): : 1832 - 1836
  • [36] Modified zeolite ZSM-5 for the methanol to aromatics reaction
    Conte, Marco
    Lopez-Sanchez, Jose A.
    He, Qian
    Morgan, David J.
    Ryabenkova, Yulia
    Bartley, Jonathan K.
    Carley, Albert F.
    Taylor, Stuart H.
    Kiely, Christopher J.
    Khalid, Karim
    Hutchings, Graham J.
    CATALYSIS SCIENCE & TECHNOLOGY, 2012, 2 (01) : 105 - 112
  • [37] Modified ZSM-5 Zeolite for Conversion of LPG to Aromatics
    Hajimirzaee, Saeed
    Mehr, Amin Soleimani
    Kianfar, Ehsan
    POLYCYCLIC AROMATIC COMPOUNDS, 2022, 42 (05) : 2334 - 2347
  • [38] PREPARATION, CHARACTERIZATION, AND CATALYSIS OF A MODIFIED ZSM-5 ZEOLITE
    GAFFNEY, AM
    JONES, CA
    SOFRANKO, JA
    TSIAO, C
    DYBOWSKI, C
    ACS SYMPOSIUM SERIES, 1993, 517 : 216 - 326
  • [39] TRANSALKYLATION OF BENZENE BY THE FRACTION OF DIISOPROPYLBENZENES ON ZSM-5 ZEOLITE CATALYSTS
    MRAVEC, D
    SCHNIERER, A
    RIECANOVA, D
    HERAIN, J
    MACHO, V
    COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1992, 57 (04) : 896 - 900
  • [40] PREPARATION, CHARACTERIZATION AND CATALYSIS OF A MODIFIED ZSM-5 ZEOLITE
    GAFFNEY, AM
    JONES, CA
    SOFRANKO, JA
    TSIAO, C
    DYBOWSKI, C
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1991, 202 : 29 - CATL
12345