Synthesis and structural characterization of tetranuclear, bimetallic sulfide nitrosyl and carbonyl clusters of the type Cp(2)M(2)M'(2)S(3,4)L(n) (M=Mo, W; M'=Fe, Co; L=NO,CO)

被引：34
|
作者：
Mansour, MA [1 ]
Curtis, MD [1 ]
Kampf, JW [1 ]
机构：
[1] UNIV MICHIGAN, DEPT CHEM, WILLARD H DOW LABS, ANN ARBOR, MI 48109 USA
来源：
ORGANOMETALLICS | 1997年 / 16卷 / 02期
关键词：
D O I：
10.1021/om960724c
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of new bimetallic sulfide clusters, Cp#(2)M(2)M'S-2(4)(NO)(2) (Cp# = C(5)Me(2)Et, C(5)Me(5), C5H5; M = Mo, W; M' = Fe, Co) have been synthesized and characterized by X-ray diffraction. Two new tungsten carbonyl clusters, Cp*2W2Co2S4(CO)(2) and Cp(2)(Et)W(2)Co(2)S(3)(CO)(5), were also synthesized and the structure of the latter determined. The structural systematics are related to the redox properties and to the electronic structure of the clusters.
引用
收藏
页码：275 / 284
页数：10
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