Friedel-Crafts type reaction of ferrocene with β-ketoesters

被引：12
|
作者：
Plazuk, D [1 ]
Zakrzewski, J [1 ]
机构：
[1] Univ Lodz, Dept Organ Chem, PL-90136 Lodz, Poland
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 67卷 / 24期
关键词：
D O I：
10.1021/jo025717e
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reaction of ferrocene with beta-ketoesters in the presence of BF3.Et2O or CF3SO3H affords beta-ferrocenyl-alpha, beta-unsaturated esters in 56-83% yield. In the case of alpha-unsubstituted-beta-ketoesters the reaction is totally E-stereoselective.
引用
收藏
页码：8672 / 8674
页数：3
相关论文
共 50 条
  • [21] Catalytic asymmetric Friedel-crafts reaction
    Tanaka, Shinji
    JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 2008, 66 (03) : 249 - 250
  • [22] The reversibility of the Friedel-Crafts reaction - Hydrogenation
    Alexander, LL
    Fuson, RC
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1936, 58 : 1745 - 1747
  • [23] Friedel-Crafts reaction in fluorous fluids
    Nakano, H
    Kitazume, T
    GREEN CHEMISTRY, 1999, 1 (04) : 179 - 181
  • [24] Concerning the Friedel-Crafts reaction.
    Heller, G
    Schulke, K
    BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1908, 41 : 3627 - 3638
  • [25] DIHALOALKANES AND HALOMETHYLPHENYLALKANES IN FRIEDEL-CRAFTS REACTION
    GELIN, R
    CHANTEGR.B
    BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE, 1971, (07): : 2527 - +
  • [26] FRIEDEL-CRAFTS REACTION OF BUTADIENE WITH BENZENE
    INUKAI, T
    JOURNAL OF ORGANIC CHEMISTRY, 1966, 31 (04): : 1124 - &
  • [27] Catalytic asymmetric Friedel-Crafts reaction
    Wang, Y
    Ding, KL
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2001, 21 (10) : 763 - 767
  • [28] Chemical engineering in Friedel-Crafts reaction
    Groggins, PH
    TRANSACTIONS OF THE AMERICAN INSTITUTE OF CHEMICAL ENGINEERS, 1930, 25 : 158 - 176
  • [29] A PHOTOCHEMICAL ALTERNATIVE TO THE FRIEDEL-CRAFTS REACTION
    KRAUS, GA
    KIRIHARA, M
    WU, Y
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 206 : 95 - ENVR
  • [30] BEHAVIOR OF POLYCHLOROCARBONYLFURANS IN FRIEDEL-CRAFTS REACTION
    GOMES, LM
    COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES SERIE C, 1974, 278 (16): : 1055 - 1058
12345