Ruthenium(II) carbonyl complexes containing tridentate Schiff bases

被引：6
|
作者：
Thangadurai, TD [1 ]
Natarajan, K [1 ]
机构：
[1] Bharathiar Univ, Dept Chem, Coimbatore 641046, Tamil Nadu, India
来源：
TRANSITION METAL CHEMISTRY | 2002年 / 27卷 / 08期
关键词：
D O I：
10.1023/A:1021310829414
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New ruthenium(II) complexes, [Ru(CO)(B)(LL') (PPh3)] (where, LL'=tridentate Schiff bases; B=PPh3, pyridine, piperidine or morpholine) have been prepared by reacting [RuHCl(CO)(PPh3)(3)] or [RuHCl(CO)(PPh3)(2)(B)] with Schiff bases containing donor groups (O, N, X) viz., salicylaldehyde thiosemicarbazone (X=S), salicylaldehyde semicarbazone (X=O), o-hydroxyacetophenone thiosemicarbazone (X=S) and o-hydroxyacetophenone semicarbazone (X=O). The new complexes were characterised by elemental analysis, spectral (i.r., H-1- and P-31-n.m.r.), data.
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页码：840 / 843
页数：4
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