An XPS investigation of thermal degradation and charring on PMMA clay nanocomposites

被引：69
|
作者：
Du, JX
Zhu, J
Wilkie, CA
Wang, JQ [1 ]
机构：
[1] Beijing Inst Technol, Sch Chem Engn & Mat Sci, Beijing 100081, Peoples R China
[2] Marquette Univ, Dept Chem, Milwaukee, WI 53201 USA
来源：
POLYMER DEGRADATION AND STABILITY | 2002年 / 77卷 / 03期
关键词：
XPS; PMMA-clay nanocomposites; thermal degradation; charring;
D O I：
10.1016/S0141-3910(02)00074-5
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Poly(methyl methacrylate)-clay nanocomposites have been studied using X-ray photoelectron spectroscopy. It is clear that as the polymer undergoes thermal degradation, the clay accumulates at the surface and the barrier properties which result from this clay accumulation have been described as the reason for the decreased heat release rate for nanocomposites. The surface composition of the clay changes as the nanocomposite is heated and the changes are affected by the organic-modification that were applied to the clay in order to prepare the nanocomposite. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：377 / 381
页数：5
相关论文
共 50 条
  • [21] The thermal degradation of nanocomposites that contain an oligomeric ammonium cation on the clay
    Su, SP
    Wilkie, CA
    POLYMER DEGRADATION AND STABILITY, 2004, 83 (02) : 347 - 362
  • [22] Effect of clay treatment on the thermal degradation of PHB based nanocomposites
    Ollier, Romina P.
    D'Amico, David A.
    Schroeder, Walter F.
    Cyras, Viviana P.
    Alvarez, Vera A.
    APPLIED CLAY SCIENCE, 2018, 163 : 146 - 152
  • [23] Rheological properties of clay/PMMA nanocomposites.
    Lee, H
    Hsieh, A
    Mckinley, G
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U526 - U526
  • [24] Investigation and modeling of the thermal conductivity of PP/clay nanocomposites and PP/MWCNT nanocomposites
    Nejad, Shahryar Jafari
    Golzary, Aboali
    E-POLYMERS, 2010,
  • [25] Investigation and modeling of the thermal conductivity of PP/clay nanocomposites and PP/MWCNT nanocomposites
    Nejad, Shahryar Jafari
    Golzary, Aboali
    E-Polymers, 2010,
  • [26] Mechanical and thermal behavior of epoxy based halloysite nano clay/PMMA hybrid nanocomposites
    Rudresh, M.
    Maruthi, B. H.
    Channakeshavalu, K.
    Nagaswarupa, H. P.
    SN APPLIED SCIENCES, 2019, 1 (07):
  • [27] Mechanical and thermal behavior of epoxy based halloysite nano clay/PMMA hybrid nanocomposites
    M. Rudresh
    B. H. Maruthi
    K. Channakeshavalu
    H. P. Nagaswarupa
    SN Applied Sciences, 2019, 1
  • [28] Effect of clay platelet dispersion as affected by the manufacturing techniques on thermal and mechanical properties of PMMA-clay nanocomposites
    Dhibar, A.K.
    Mallick, S.
    Rath, T.
    Khatua, B.B.
    Journal of Applied Polymer Science, 2009, 113 (05): : 3012 - 3018
  • [29] Effect of Clay Platelet Dispersion as Affected by the Manufacturing Techniques on Thermal and Mechanical Properties of PMMA-Clay Nanocomposites
    Dhibar, A. K.
    Mallick, S.
    Rath, T.
    Khatua, B. B.
    JOURNAL OF APPLIED POLYMER SCIENCE, 2009, 113 (05) : 3012 - 3018
  • [30] Effect of magnesium dihydroxide nanoparticles on thermal degradation and flame resistance of PMMA nanocomposites
    Laoutid, Fouad
    Sonnier, Rodolphe
    Francois, Damien
    Bonnaud, Leila
    Cinausero, Nicolas
    Cuesta, Jose-Marie Lopez
    Dubois, Philippe
    POLYMERS FOR ADVANCED TECHNOLOGIES, 2011, 22 (12) : 1713 - 1719
12345