Transition-metal-catalyzed aldehydic C-H activation by azodicarboxylates

被引：49

作者：

Lee, DS ^{[1
]}

Otte, RD ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2004年 / 69卷 / 10期

关键词：

D O I：

10.1021/jo035456o

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Rhodium acetate-catalyzed hydroacylation between aldehydes and an activated form of N=N bond was achieved under mild conditions to provide efficient access to a variety of hydrazino imides. Good selectivity for the aldehydie C-H activation relative to the ene-type reaction was observed with aldehydes having unsaturation both at terminal and internal positions.

引用

页码：3569 / 3571

页数：3

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