Polymer electrolyte using in situ quanternization for all solid-state dye-sensitized solar cells

被引：5
|
作者：
Xiang, Wanchun [1 ,2 ]
Zhou, Shuhua [1 ]
Yin, Xiong [1 ,2 ]
Xiao, Xurui [1 ]
Lin, Yuan [1 ]
Fang, Shibi [1 ]
机构：
[1] Chinese Acad Sci, Key Lab Photochem, Inst Chem, Beijing 100080, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
来源：
POLYMERS FOR ADVANCED TECHNOLOGIES | 2009年 / 20卷 / 06期
关键词：
in situ quanternization reaction; latent crosslinked precursor; all solid-state electrolyte; dye-sensitized solar cell; CROSS-LINKED GEL; EFFICIENT; CONDUCTIVITY; FILMS;
D O I：
10.1002/pat.1375
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Polymer electrolyte through in situ quanternization reaction by oligo-siloxane containing quanternary ammonium groups was synthesized for all solid-state dye-sensitized solar cells (DSSCs). These two latent crosslinked precursors are oligo-organosiloxane grafting oligo-ethylene oxide and propylene oxide dimethylamine (OEA) and the oligo-organosiloxane grafting oligo-ethylene oxide and propylene oxide bromide (OEB). This chemically crosslinked electrolyte shows good ambient conductivity of 2.6 x 10(-4)S/cm when incorporating appropriate amount of 1-iodide oligo-ethylene glycol monomethylether (IOEGMME) as an additive. Photoelectrochemical performances for different electrolytes were also analyzed. Copyright (C) 2009 John Wiley & Sons, Ltd.
引用
收藏
页码：519 / 523
页数：5
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