Aqueous Flow Hydroxycarbonylation of Aryl Halides Catalyzed by an Amphiphilic Polymer-Supported Palladium-Diphenylphosphine Catalyst

被引：11

作者：

Osako, Takao ^{[1
]}

Kaiser, Reinhard

Torii, Kaoru

Uozumi, Yasuhiro ^{[1
]}

机构：

[1] IMS, Okazaki, Aichi 4448787, Japan

来源：

SYNLETT | 2019年 / 30卷 / 08期

关键词：

continuous; flow reaction; hydroxycarbonylation; aryl halides; palladium catalysis; benzoic acids; catalyst support; heterogenous catalysis; CARBONYLATION REACTIONS; CHEMISTRY; HYDROGENATION; CO;

D O I：

10.1055/s-0037-1611769

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An aqueous continuous-flow reaction system is developed for the palladium-catalyzed hydroxycarbonylation of aryl halides. Flow hydroxycarbonylation of aryl halides in aqueous solution proceeds efficiently in a flow reactor containing a palladium-diphenylphosphine complex immobilized on an amphiphilic polystyrene-poly( ethylene glycol) resin to give the corresponding benzoic acids in excellent yields.

引用

页码：961 / 966

页数：6

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