From cyclic polyenes to carbohydrates:: synthesis of the hexose sugar β-allose and its 2C-branched homologue from cyclooctatetraene

被引：14

作者：

Mehta, G ^{[1
]}

Pallavi, K ^{[1
]}

机构：

[1] Indian Inst Sci, Dept Organ Chem, Bangalore 560012, Karnataka, India

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 20期

关键词：

D O I：

10.1016/j.tetlet.2004.03.129

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In an unconventional but interesting synthetic enterprise, the commercially available hydrocarbon cyclooctatetraene (COT) has been elaborated to the rare hexose sugar (DL)-beta-allose and its 2C-branched analogue. The synthetic sequence delineated here is notable for its high regio- and stereoselectivity and is flexible enough to enable access to polyoxygenated systems, hexose sugars, and their siblings from a cyclic polyene precursor. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：3865 / 3867

页数：3

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