From cyclic polyenes to carbohydrates:: synthesis of the hexose sugar β-allose and its 2C-branched homologue from cyclooctatetraene

被引：14
|
作者：
Mehta, G [1 ]
Pallavi, K [1 ]
机构：
[1] Indian Inst Sci, Dept Organ Chem, Bangalore 560012, Karnataka, India
来源：
TETRAHEDRON LETTERS | 2004年 / 45卷 / 20期
关键词：
D O I：
10.1016/j.tetlet.2004.03.129
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In an unconventional but interesting synthetic enterprise, the commercially available hydrocarbon cyclooctatetraene (COT) has been elaborated to the rare hexose sugar (DL)-beta-allose and its 2C-branched analogue. The synthetic sequence delineated here is notable for its high regio- and stereoselectivity and is flexible enough to enable access to polyoxygenated systems, hexose sugars, and their siblings from a cyclic polyene precursor. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3865 / 3867
页数：3
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