Modification of anion-exchange membranes for vanadium redox flow battery applications

被引:104
|
作者
Mohammadi, T [1 ]
Skyllas-Kazacos, M [1 ]
机构
[1] UNIV NEW S WALES, SCH CHEM ENGN & IND CHEM, SYDNEY, NSW 2052, AUSTRALIA
基金
澳大利亚研究理事会;
关键词
ion-exchange membranes; sulfonation; vanadium redox batteries; batteries; water transfer;
D O I
10.1016/S0378-7753(96)02463-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Modification of the Selemion AMV and New Selemion (Type 2) anion-exchange membranes (Asahi Glass, Japan) has improved their water transport properties in the vanadium redox cell. The AMV membrane is sulfonated using concentrated sulfuric acid, while poly (sodium-4-styrenesulfonate) (Aldrich, USA, mol. wt. similar to 70 000) is incorporated into the New Selemion (Type 2) membrane. A significant reduction in the amount of water transport across the membranes during operation of the vanadium redox battery is achieved.
引用
收藏
页码:179 / 186
页数:8
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