Allylation of carbonyl compounds mediated by nanometer-sized bismuth in water

被引：18
|
作者：
Xu, XL
Zha, ZG
Miao, Q
Wang, ZY [1 ]
机构：
[1] Columbia Univ, Dept Chem, New York, NY 10027 USA
[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China
来源：
SYNLETT | 2004年 / 07期
关键词：
allylation; carbonyl compounds; water; aromatic; stereoselectivity;
D O I：
10.1055/s-2004-822924
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
It is found that nanometer-sized bismuth mediates the allylation of carbonyl compounds in water to afford the corresponding homoallylic alcohol in high yields. Nanometer-sized bismuth is much more effective than regular bismuth powder in this reaction.
引用
收藏
页码：1171 / 1174
页数：4
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