Thermodynamic Properties of Al-La-Ni Melts

被引:1
|
作者
Kudin, V. G. [1 ]
Shevchenko, M. O. [1 ]
Ivanov, M. I. [1 ]
Berezutskii, V. V. [1 ]
Subotenko, P. M. [1 ]
Sudavtsova, V. S. [1 ]
机构
[1] Natl Acad Sci Ukraine, Frantsevich Inst Problems Mat Sci, Kiev, Ukraine
关键词
thermodynamic properties; melt; aluminum; lanthanum; nickel; ALLOYS; ND;
D O I
10.1007/s11106-017-9845-0
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The mixing enthalpies of liquid ternary Al-La-Ni alloys are determined by isoperibol calorimetry for sections (Al0.42La0.58)(1-x)Nix (0 < x < 0.27) at 1430 K and (La0.25Ni0.75)(1-x)Al-x at 1770 K (0 < < x(Al) < 0.3) or 1800 K (0.3 < x(Al) < 0.39). The experimental mixing enthalpies and those calculated with the Redlich-Kister model are characterized by exothermic effects. The minimum mixing enthalpy of the melts is -54 kJ/mol for composition Al0.4La0.2Ni0.4.
引用
收藏
页码:603 / 611
页数:9
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