Asymmetric epoxidation of non-functionalized alkenes using transition metal complexes

被引:7
|
作者
Abdi, SHR [1 ]
Kureshy, RI [1 ]
Khan, NH [1 ]
Jasra, RV [1 ]
机构
[1] Cent Salt & Marine Chem Res Inst, Silicates & Catalysis Discipline, Bhavnagar 364002, Gujarat, India
关键词
asymmetric catalysis; chiral; non-functionalized alkenes; transition metals; salen; epoxide;
D O I
10.1023/B:CATS.0000038537.27684.b4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Asymmetric catalytic epoxidation of alkenes such as styrenes, chromenes and indene using transition metal complexes both inhomogeneous and heterogeneous phase has been discussed in this review. The various strategies to make the catalysts recyclable by introducing in-built phase transfer ability, converting these to dimeric form, exchanging into clays and supporting on polymeric or inorganic supports are discussed at length.
引用
收藏
页码:187 / 197
页数:11
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